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1 D The balanced equation is: 3Fe(OH)2 (s) + 2 H3PO 4 (aq ) Fe 3 (PO 4 )2 ( s) + 6 H 2O (l ) 2 B Carbonates produce carbon dioxide gas in the presence of an acid 3 D Aluminum hydroxide, Al(OH)3, forms initially but then dissolves to form the Al(OH)4 ion 4 A Aqueous solutions of Cu are normally blue Iron ions give a variety of colors, but are normally colorless, or nearly so, in the absence of complexing agents All the others are colorless 5 B Lead(II) carbonate is insoluble, so its formula should be left as PbCO3 Hydrochloric acid is a strong acid so it should be written as + separate H and Cl ions Lead(II) chloride, PbCl2, is insoluble, and carbonic acid, H2CO3, quickly decomposes to CO2 and H2O 6 C The balanced chemical equation is: 3 Cu + 8 HNO3 3 Cu( NO3 )2 + 2 NO + 4 H 2O The copper is below hydrogen on the activity series, so H2 cannot be formed by this acid metal reaction Nitric acid is an oxidizing 2+ agent, which will oxidize copper to Cu giving Cu(NO3)2 7 A Acetic acid is a weak acid; as such it should appear as HC2H3O2 Potassium hydroxide is + a strong base so it will separate into K and OH ions The potassium ion is a spectator ion, and is left out of the net ionic equation 8 E Aqueous ammonia contains NH3 The reaction produces the silver ammonia complex, + [Ag(NH3)2] 9 A The reaction is: 2 K + 2 H 2O 2 KOH + H 2 KOH is a water-soluble strong base, not an acid As a strong base it will react with an acid Iron(II) hydroxide, Fe(OH)2, is insoluble and will precipitate

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N2(g) + C2H2(g)

'2HCN(g)

If the system initially is an equimolar mixture of nitrogen and acetylene, what is the composition of the system at equilibrium What would be the effect of doubling the pressure Assume ideal gases

Before a game against the arch-rival Bears in 1967, he skipped the high-volume exhortation that many of the Packers must have been expecting Instead, he told a joke, keying off the fact that the area around Green Bay had been settled many years earlier by Belgian immigrants Did you ever hear why Belgians are so strong

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10 E Aqueous ammonia contains NH3 The charges on each side of the reaction arrow must be equal 11 B Neither B nor C is soluble in water Only B will react will nitric acid, and will dissolve 12 D The magnesium chloride gives 020 moles of chloride ion, and the potassium chloride gives 010 moles of chloride ion A total of 030 moles of chloride will react with 015 moles of lead, 2+ because two Cl require one Pb 13 D The HCl will react with one-half the silver to halve the concentration The doubling of the volume halves the concentration a second time 14 B All the potassium and nitrate ions remain in solution However, two nitrate ions are produced per solute formula as opposed to only one potassium ion The lead and potassium would be equal, but some of the lead is precipitated as PbCl2 15 C Ammonia, as a base, will precipitate the metal hydroxides Chromate, sulfide, and chloride ions will precipitate one or more of the ions 16 E Chlorine is an oxidizing agent It is capable of oxidizing both B and E Answer B gives I2, which is brownish in water and purplish in methylene chloride Answer E gives reddish Br2

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1313 The following reaction reaches equilibrium at 62315 K (350 C) 3 bar:

If the system initially contains 15 mol H2 for each mole of acetaldehyde, what is the composition of the system at equilibrium What would be the effect of reducing the pressure to 1 bar Assume ideal gases

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